A chronicle of the life of 18th century aristocrat Georgiana (Kiera Knightly), Duchess of Devonshire, who reviled for her extravagant political and personal lives. She is a vibrant beauty and celebrity of her time.

But she is trapped in an unhappy triangle with her husband and his live-in mistress. She falls passionately in love with an ambitious young politician, and the affair causes a bitter conflict with her husband and threatens to erupt into a scandal.

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